Diglycerides, vegetable-oil monoglycerides and diglycerides (CAS 97488-91-0) — Citrus Functional Note Fragrance Ingredient
Diglycerides, vegetable-_oil monoglycerides and diglycerides
CAS 97488-91-0
What Is Diglycerides, vegetable-_oil monoglycerides and diglycerides?
Diglycerides are synthetic emulsifiers derived from vegetable oils. You’ll find them in processed foods, cosmetics, and pharmaceuticals where they help blend oil and water. While odorless themselves, they play a crucial role in stabilizing fragrances by preventing separation of aromatic components in complex formulations.
Safety Profile
GENERALLY SAFEWhat Does Diglycerides, vegetable-_oil monoglycerides and diglycerides Smell Like?
As a functional ingredient rather than an aromatic compound, diglycerides are odorless. Their value lies in their molecular structure – the partial glyceride backbone allows them to act as bridges between polar and non-polar substances. In perfumery, this translates to improved solubility of essential oils and better emulsion stability in alcohol-based sprays.
Chemistry, Properties & Perfumer Guide
The Chemistry
Diglycerides consist of a glycerol molecule esterified with two fatty acid chains, typically derived from plant sources like palm or soybean oil. They’re produced through controlled hydrolysis of triglycerides or via glycerolysis. The specific fatty acid profile determines their hydrophilic-lipophilic balance (HLB), which ranges from 3-7 for common food-grade variants. Their amphiphilic nature makes them excellent stabilizers for oil-water interfaces.
Physical & Chemical Properties
| Appearance | Pale yellow viscous liquid |
|---|---|
| HLB Range | 3-7 |
| Solubility | Dispersible in both oil and water phases |
Perfumer Guide
| Application | Typical % | Range | Notes |
|---|---|---|---|
| Emulsion Stabilization | 0.5-2% | Up to 5% | Prevents fragrance oil separation |
| Spray Formulations | 1-3% | Up to 8% | Improves mist characteristics |
Classic Accords
Tip: Use with polysorbates for complete emulsion systems in alcohol-based perfumes.
Alternatives & Comparisons
Safety, Regulatory & Sustainability
⚠ Regulatory Disclaimer
General reference only. Consult current IFRA Standards Library before formulating.
IFRA Status
No IFRA restrictions – classified as processing aid rather than fragrance ingredient.
RIFM Assessment
Not evaluated by RIFM as it’s not a direct fragrance material.
Sustainability
Most commercial diglycerides come from RSPO-certified palm oil or non-GMO soybean sources. The glycerolysis process is relatively energy-efficient compared to complete triglyceride hydrolysis. Recent advances allow production from waste cooking oil streams, improving circular economy potential.
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References
- McClements, D.J. (2015). Food Emulsions. CRC Press.
- EFSA Panel on Food Additives (2017). Re-evaluation of mono- and diglycerides of fatty acids. EFSA Journal. DOI: 10.2903/j.efsa.2017.5045
Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.
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